I'm one of the maintainers for getrandom, a no_std library which attempts to define the "standard" way to get cryptographic entropy on every Rust target. The rand crate and others use this crate under the hood.
As far as I can tell HermitCore doesn't expose or have a way to get OS-based randomness. For that reason, we don't currently support Hermit.
Are users simply expected to call RDRAND? This is reasonable, provided that HermitCore is x86_64 only.