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pytrr does currently not support the .xtc format. This could be added but would require some more work.
Note that xdrlib can probably be used (and it could possibly be used for .trr files as well).
For the .xtc format see:
[1] http://manual.gromacs.org/online/xtc.html
[2] http://www.gromacs.org/Developer_Zone/Programming_Guide/XTC_Library